翻訳と辞書
Words near each other
・ ACF Trani 80
・ ACF2
・ ACFAS
・ ACFC
・ ACFD
・ ACFI
・ Acfred I of Carcassonne
・ Acfred II of Carcassonne
・ Acetolactic acid
・ Acetolactone
・ Acetomicrobium
・ Acetone
・ Acetone (band)
・ Acetone (data page)
・ Acetone (disambiguation)
Acetone azine
・ Acetone carboxylase
・ Acetone cyanohydrin
・ Acetone oxime
・ Acetone peroxide
・ Acetone thiosemicarbazone
・ Acetonedicarboxylic acid
・ AcetoneISO
・ Acetonema
・ Acetone–butanol–ethanol fermentation
・ Acetonide
・ Acetonitrile
・ Acetonitrile (data page)
・ Acetophenazine
・ Acetophenone


Dictionary Lists
翻訳と辞書 辞書検索 [ 開発暫定版 ]
スポンサード リンク

Acetone azine : ウィキペディア英語版
Acetone azine

|Section2=
|Section5=
|Section6=
}}
Acetone azine is the simplest ketazine. It is an intermediate in some hydrazine manufacturing processes.
== Synthesis ==

Acetone azine can be prepared from acetone and hydrazine:
:2 (CH3)2CO + N2H4 → 2 H2O + ()2
It can also be produced from acetone (2 eq.), ammonia (2 eq.) and hydrogen peroxide (1 eq.).〔. 〕 The first step is the formation of acetone imine, Me2C=NH; this is then oxidized by hydrogen peroxide through a complex mechanism to give 3,3-dimethyloxaziridine, which reacts with a further molecule of ammonia to produce acetone hydrazone. The hydrazone then condenses with a further molecule of acetone to produce the azine. The acetone azine product is distilled out of the reaction mixture as its azeotrope with water (''n''(H2O)/''n''(azine) ≈ 6).

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
ウィキペディアで「Acetone azine」の詳細全文を読む



スポンサード リンク
翻訳と辞書 : 翻訳のためのインターネットリソース

Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.